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Spectroscopic Evidence for a Dinitrogen Complex of Gallium and Estimation of the Ga—N2 Bond Strength.

✍ Scribed by Hans-Joerg Himmel; Nicole Hebben

Publisher
John Wiley and Sons
Year
2006
Weight
9 KB
Volume
37
Category
Article
ISSN
0931-7597

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Spectroscopic Evidence for a Dinitrogen
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✍ Hans-Jörg Himmel; Nicole Hebben 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 306 KB

## Abstract Matrix‐isolation experiments were performed to study the interaction between Ga atoms and N~2~ by using Raman and UV/Vis spectroscopies for detection and analysis. It was revealed that a weak complex is formed, for which resonance Raman spectra were obtained. Several overtones were sigh

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## Abstract Reaction of the side‐on end‐on dinitrogen complex [{(NPN)Ta}~2~(μ‐H)~2~(μ‐η^1^:η^2^‐N~2~)] (1; in which NPN=(PhNSiMe~2~CH~2~)~2~PPh), with the Lewis acids XR~3~ results in the adducts [{(NPN)Ta}~2~(μ‐H)~2~(μ‐η^1^:η^2^‐NNXR~3~)], XR~3~=GaMe~3~ (2), AlMe~3~ (3), and B(C~6~F~5~)~3~ (4). Th