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Spectroscopic detection of particles from shock-wave-induced decomposition of SiH4

✍ Scribed by J. Steinwandel; J. Hoeschele


Book ID
103022866
Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
459 KB
Volume
116
Category
Article
ISSN
0009-2614

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✦ Synopsis


Particle formatlon from silane pyrolysis was stud& m a shock tube Molecular and atorruc specres (SIH,. SIH. SI,, H,. SI. H) were rdenllfied by thermal Induced fluorescence at temperatures exceedmg 3ooL, K. At temperatures below 2500 K, s~hcon cluster formation was detected by optical extmction measurements


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State-selective spectroscopic detection
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The decomposition mechanism of SiHa('B, ) formed after IR multiple-photon dissociation of SiH., has been investigated by simultaneous acquisition of spontaneous chemiluminescence of SiHr radicals and state-selective two-photon laser-induced fluorescence spectra of the atomic silicon produced Evidenc