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Spectroscopic detection of asymmetric highly oxidized intermediates in disproportionation reaction of iron(III) porphyrin π-cation radicals

✍ Scribed by Krystyna Rachlewicz; Lechosław Latos-Grażyński


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
73 KB
Volume
59
Category
Article
ISSN
0162-0134

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## Abstract We have shown previously that iodosylbenzene–iron(III) porphyrin intermediates (2) are generated in the reactions of oxoiron(IV) porphyrin π‐cation radicals (1) and iodobenzene (PhI), that 1 and 2 are at equilibrium in the presence of PhI, and that the epoxidation of olefins by 2 afford