Spectroscopic characterization of alumina supported transition metal carbonyl catalysts. 2. W(CO)6 and Cr(CO)6
β Scribed by A. Kuzusaka; R.F. Howe
- Publisher
- Elsevier Science
- Year
- 1980
- Weight
- 572 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0304-5102
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π SIMILAR VOLUMES
The reaction of Na 2 [Fe(CO) 4 ] with Br 2 CF 2 in npentane generates a mixture of the compounds (CO) 3 Fe(l-CO) 3Β±n (l-CF 2 ) n Fe(CO) 3 (2, n = 2; 3, n = 1) in low yields with 3 as the main product. 3 is obtained free from 2 by reacting Br 2 CF 2 with Na 2 [Fe 2 (CO) 8 ]. The non-isolable monomeri
Using IR spectroscopic data of Cr(CO)6 adsorbed on different surface centers on gamma-Al2O3, we were able to calculate isotherms for adsorption on these centers. Linear relations were observed between spectroscopic data (position, extinction coefficient, and half-width values) of corresponding bands