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Spectroscopic characterization of alumina-supported transition metal carbonyl catalysts. 1. Mo(CO)6

✍ Scribed by A. Kazusaka; R.F. Howe

Publisher
Elsevier Science
Year
1980
Weight
980 KB
Volume
9
Category
Article
ISSN
0304-5102

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Tungsten and molybdenum were introduced in β₯-Al 2 O 3 and Pd/β₯-Al 2 O 3 using metalcarbonyls [W(CO) 6 and Mo(CO) 6 ] photoactivation. DRIFTS FT-IR spectra of the surfaces prior to thermal decomposition reveal the presence of unstable metalsubcarbonyl species, in contrast with the ones found previous