## Abstract Heavy‐metal‐oxide (HMO) glasses and vitroceramics of [3Bi~2~O~3~·2PbO] and 20MnO·80[3Bi~2~O~3~·2PbO] compositions were investigated by Raman, infrared (IR) and electron paramagnetic resonance (EPR) spectroscopies. Changes in the local structure of the heavy‐metal host glass induced by m
Spectroscopic analysis of praseodymium and erbium ions in heavy metal fluoride and oxide glasses
✍ Scribed by Wojciech A. Pisarski
- Publisher
- Elsevier Science
- Year
- 2005
- Tongue
- English
- Weight
- 216 KB
- Volume
- 744-747
- Category
- Article
- ISSN
- 0022-2860
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✦ Synopsis
Spectroscopic analysis of Pr 3C and Er 3C ions in fluoride and oxide systems belonging to the same heavy metal glass family has been reported. From absorption and emission spectra using Judd-Ofelt theory various spectroscopic parameters like radiative transition rates, luminescence lifetimes, radiative quantum efficiencies, spectral line widths as well as emission cross-sections are determined. Selected examples for the spectroscopic behavior of both optical glasses are discussed in relation to the practical application of these materials as a potential laser-active media in the visible and infrared spectral region.
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