Spectrophotometric measurements of metal complex formation at high temperatures: the stability of Mn(II) chloride species
✍ Scribed by O.M Suleimenov; T.M Seward
- Book ID
- 117072541
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 781 KB
- Volume
- 167
- Category
- Article
- ISSN
- 0009-2541
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## Abstract The stopped‐flow technique was used to measure the rates of formation and dissociation of tetrahedral [ML~2~] complexes (M^2+^=Ni^2+^ or Co^2+^) of four bidentate S~2~‐donor ‘dithioimidodiphosphato’ ligands L^−^ (HL=[R^1^R^2^P(S)]NH[P(S)R^3^R^4^], R^1^ to R^4^=alkyl) at 25.0° in MeOH/