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Spectrophotometric investigations of aqueous solutions at elevated temperatures. Effect of temperature on the stability constants of the tris complexes of 1,10-phenanthroline, 5-nitro-1,10-phenanthroline and 2,2′-bipyridyl with iron (II)

✍ Scribed by Alexander, Roger D.; Buisson, David H.; Dudeney, A. William L.; Irving, Roger J.

Book ID
115479581
Publisher
The Royal Society of Chemistry
Year
1978
Weight
636 KB
Volume
74
Category
Article
ISSN
0300-9589

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Effect of cosolvent on the volume of act
Effect of cosolvent on the volume of activation for base hydrolysis of tris(1.10-phenanthroline)- and tris (2.2′-bipyridine)iron(II) complexes
✍ John Burgess; Colin D. Hubbard 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 137 KB 👁 2 views

The kinetics of the base hydrolysis of Fe(phen) 3 2ϩ and Fe(bipy) 3 2ϩ (phen ϭ 1,10phenanthroline and bipy ϭ 2,2'-bipyridine) in some aqueous alcohol mixtures at ambient and elevated pressures (up to 1kbar) have been monitored spectrophotometrically at 25.0ЊC. For a given pressure, the alcohol cosol