Spectrofluorometric Probe Method for Examining Preferential Solvation in Binary Solvent Mixtures
β Scribed by Acree, William E.; Wilkins, Denise C.; Tucker, Sheryl A.
- Book ID
- 115362188
- Publisher
- Society for Applied Spectroscopy
- Year
- 1993
- Tongue
- English
- Weight
- 425 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0003-7028
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The use of chemical probes for the characterization of chemical properties is explored for aprotic binary solvent mixtures. The solvatochromic indicators N,N-diethyl-4-nitroaniline, 4-nitroanisole, 4-nitroaniline and 4nitrophenol were used to characterize binary solvent mixtures of a polar aprotic h
The preferential solvation of neutral and ionic organic species (phenol, nitroanilines, N-methylbutyramide, 1,4-dioxane, acetate and tetraalkylammonium ions) in binary solvent mixtures (aqueous CH 3 CN, DMSO, EtOH, 1-PrOH, CH 3 CON(CH 3 ) 2 ; CH 2 Cl 2 /Et 2 O; 1,4-dioxane/benzene; cyclohexane/THF)