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Spectrochemical study of the electron transfer reaction in the tetraazamacrocyclic copper complex series

โœ Scribed by N. I. Kovalenko; A. I. Vrublevskii; T. V. Karmanova; E. P. Petryaev


Book ID
104873429
Publisher
Springer US
Year
1989
Tongue
English
Weight
449 KB
Volume
50
Category
Article
ISSN
0021-9037

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ESR studies of electron-transfer reactio
โœ R.F. Adams; T.L. Staples; M. Szwarc ๐Ÿ“‚ Article ๐Ÿ“… 1970 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 221 KB

The exchange between durosemiquinone triplet-ions (DQ; ,2Na+) and the parent quinone in THF was studied. Both sodium ions are transferred in the process, and ihe ESR spectrum in the presence of 2M duroquinone collapses into '/ lines. The sodium coupling constant in this spectrum is 1.93 MHz whereas