Spectral and redox behaviour of copper(II) bis(benzimidazolyl)-tetra- and pentathioether complexes
β Scribed by Usha Sivagnanam; Mallavan Palaniandavar; Anthony W. Addison
- Book ID
- 103569026
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 97 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0162-0134
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## Abstract The dinuclear Cu^II^ and Ni^II^ complexes of __meta__βxylyl and pyridyl biscyclen and biscyclam have been prepared and characterised in solution by means of UV/Visible spectra, electrochemical and EPR studies. Xβray structures of copper biscyclen complexes have been obtained. The compar
Abatmet -In aqueous potassium nitrate the complexes Cu(dip)(gly) Cl. 1.5 H,O, Cu(dip)(alan) Cl. 1.5 H,O, Cu(dip)(val) Cl.3H,O, Cu(dip)(ser) Cl H,O have been observed to undergo single step two electron irreversible electroreduction at dme. From the characteristics of irreversible wave, the rate cons