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Spectral and Quantum‐Chemical Investigation of the Influence of the Spatial Structure of a Polymeric Complex on the Mechanism of Catalytic Oxidation of Sulfur Dioxide with Oxygen

✍ Scribed by V. S. Emel'yanova; G. A. Yuldasheva; K. A. Zhubanov; T. V. Shakieva


Book ID
110386844
Publisher
Springer US
Year
2001
Tongue
English
Weight
71 KB
Volume
68
Category
Article
ISSN
0021-9037

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## Abstract The catalytic activity of an aluminum complex/silanol system was found to vary with the aluminum ligand as follows: β‐diketonate < β‐ketoester anion < ortho‐carbonylphenolate. Aluminum complexes with electron donating groups conjugated with a carbonyl group had higher catalytic activity