Effect of substituents on the electronic structure of cyclic oxides and its change in the interaction of oxides with an electron acceptor. Quantum chemical investigation

Correlation between the electronic struc

Correlation between the electronic structure of cyclic oxides and their ability for undergoing anionic polymerization. Quantum chemical investigation

✍ N. M. Geller; Yu. Ye. Eizner; V. A. Kropachev 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 English ⚖ 277 KB 👁 1 views

I t is shown that cyclic oxides can be anionically polymerized if the lowest vacant molecular orbital (LVMO) of a C, atom contains a region which can effectively overlap by the electronic cloud of the anionic active centre. This means that LVMO must be a-symmetrical and a t least one of the C, atoms