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Specific inactivation of isomerohydrolase activity by 11-cis-retinoids

✍ Scribed by Deviprasad R Gollapalli; Robert R Rando

Book ID
108497877
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
332 KB
Volume
1651
Category
Article
ISSN
1570-9639

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## Abstract A selective total synthesis of [11,12‐^3^H]‐9‐__cis__‐retinoic acid 1 at a specific activity of 46 Ci/mmole is described. The alkyne 4, efficiently prepared in two steps from readily available starting materials, was partially reduced to 9,11‐di‐__cis__‐retinoic acid 3 with both deuteri