We have developed a family of receptors designed to bind flavin derivatives using specific hydrogen bond interactions. These synthetic host molecules provide a model for specific hvoenzyme-cofactor interactions, allowing isolation and observation of the effects of hydrogen bonding on flavin NMR. We
✦ LIBER ✦
Specific deuteration effects on carbon-13 NMR relaxation data of amido-type systems
✍ Scribed by M. J. Shapiro; A. D. Kahle
- Publisher
- John Wiley and Sons
- Year
- 1979
- Tongue
- English
- Weight
- 205 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
The effect of deuterium substitution in amido‐systems is explored. For benzamide, both positive and negative changes in T^DD^~1~ are observed. A method for structure elucidation of these and related systems is presented.
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## Abstract The potential of branch length discrimination for branches containing six and more carbons via bulk NMR relaxation properties in the melt‐state has been explored. A systematic increase in the ^13^C spin‐lattice relaxation time (__T__) of the terminal branch carbons __1__ and __2__ was o