Specific deamination of 4-amino-1,2,4-triazin-5(4H)-ones by catalytic oxidation with t-butylhydroperoxide. A chemical model for metabolism of 1,2,4-triazine herbicides
✍ Scribed by Y. Nakayama; Y. Sanemitsu; H. Yoshioka; A. Nishinaga
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 139 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4039
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The first reported solid-phase synthesis of 3-amino-1,2,4-triazin-5(4H)-ones is described. Reactions of polymer-bound isothiourea with 2,3-diaza-3-pentenedioic anhydride forms 3-amino-1,2,4-triazin-5(4H)-ones in good yields and high purity.
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