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Speciation of cobalt, nickel and zinc-ethylenediaminediacetate complexes with N-heterocycle ligand – Synthesis, spectroscopic and structural studies

✍ Scribed by Jin-Long Ji; Li-Qing Huang; Yan Cai; La-Jia Yu; Zhao-Hui Zhou

Publisher: Elsevier Science
Year: 2011
Tongue: English
Weight: 732 KB
Volume: 994
Category: Article
ISSN: 0022-2860
DOI: 10.1016/j.molstruc.2011.02.057

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## Abstract Divalent nickel, cobalt and iron complexes {[(bmppa)Ni(CH~3~CN)](ClO~4~)~2~ (1), [(bmppa)Co(CH~3~CN)](ClO~4~)~2~ (2), [(bmppa)Fe(CH~3~CN)](ClO~4~)~2~ (3)} of an amide‐appended N~2~S~2~‐donor ligand {bmppa = __N__,__N__‐bis(2‐methylthio)ethyl‐__N__‐[(6‐pivaloylamido‐2‐pyridyl)methyl]amin