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Special features of the mechanism of the ruthenium-compounds-catalyzed oxidation of malonic acid with cerium(IV)

✍ Scribed by K. B. Yatsimirskii; L. P. Tikhonova; L. N. Zakrevskaya

Book ID
112364004
Publisher
Springer
Year
1976
Tongue
English
Weight
527 KB
Volume
12
Category
Article
ISSN
0040-5760

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✍ Asim K. Das; Mahua Das πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 478 KB πŸ‘ 1 views

The kinetics of oxidation of ethanol by cerium(1V) in presence of ruthenium(II1) (in the order of mol dm-3) in aqueous sulfuric acid media have been followed at different temperatures (25-40Β°C). The rate of disappearance of cerium(1V) in the title reaction increases sharply with increasing [CzH50H]