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Sonogashira Coupling Reaction with Palladium Powder, Potassium Fluoride in Aqueous Media.

✍ Scribed by Lei Wang; Pinhua Li

Publisher
John Wiley and Sons
Year
2004
Weight
114 KB
Volume
35
Category
Article
ISSN
0931-7597

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✍ Xiao-Feng Wu; Helfried Neumann; Matthias Beller πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 173 KB

## Abstract A general palladium‐catalyzed carbonylative cross‐coupling reaction of benzyl chlorides with potassium aryltrifluoroborates in water has been developed. Applying this improved methodology 16 different 1,2‐diarylethanones have been synthesized in 40–89% yield.