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Some Thoughts about Bond Energies, Bond Lengths, and Force Constants

✍ Scribed by Dieter Cremer; Anan Wu; Andreas Larsson; Elfi Kraka


Publisher
Springer-Verlag
Year
2000
Tongue
English
Weight
190 KB
Volume
6
Category
Article
ISSN
1610-2940

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Using 25 accurately known bond-stretching force constants and bond lengths for 23 molecules, a relation of the form: F' = 37.3 r 5 35 has been obtained for carbon-nitrogen bonds. The root-mean-square deviation between the force constant values reported in the literature and those calculated from the