Isolated CH stretching frequencies, bond lengths and dissociation energies in some haloalkanes and alkenes
β Scribed by M.W. Mackenzie
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 273 KB
- Volume
- 40
- Category
- Article
- ISSN
- 1386-1425
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Infrared spectra in the CH stretching region have been obtained from partially deuterated methyl, dimethyl and trimethyl germanes and arsines, ethyl germane, MeGeH\*X, where X = F, Cl, Br, I and MeGeHQ. In general, the isolated CH stretching frequencies show patterns of behaviour with respect to the
By photolyzing (CF,H),CO and (CFH,),CO the hydrogen atom abstraction reactions of CF,H radicals with (CF,H),CO, H, , D, , CH, , C,H, , n-C,H,, and iso-C,H1,, and the reactions of CFH, radicals with (CFH,),CO and n-C,H,, , have been studied. Arrhenius parameters for these reactions are compared with
## Abstract The ability to use calculated OH frequencies to assign experimentally observed peaks in hydrogen bonded systems hinges on the accuracy of the calculation. Here we test the ability of several commonly employed model chemistriesβHF, MP2, and several density functionals paired with the 6β3