We use a recently proposed method to calculate the electric ~olarizabilities of the hydrogen molecule and the hydrogen molecular ion We solve the first-order and second+xder perturbation equations by variational procedures and we use the solution of the second-order perturbation equation to improve
Some remarks on the calculation of the polarizability of a molecule
β Scribed by M.M. Biedermann
- Book ID
- 104163087
- Publisher
- Elsevier Science
- Year
- 1938
- Weight
- 144 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0031-8914
No coin nor oath required. For personal study only.
β¦ Synopsis
A wave-mechanical discussion of the theory of Silberstein on polarisation of molecules is given.
It is shown, that the additional polarisation of one atom by the electric dipole induced in ~.nother, can be described by using the perturbed wave function in the second-order approximation. *) To avoid difficulties in applying the perturbation theory we may assume, that the electric field is only appreciable in a restricted part of space. The unit of lectric charge is that of the proton.
π SIMILAR VOLUMES
A varMlon-perturbation method has been used to calculate the dynamic polarizabllities al(w) and Q,,(W) of the hydrogen molecule. Values have been obtained for frequencies below the first exatation for a fned bond len@h of I.4 au.