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Some reactions of ω-chloroacetophenone and ω-chloro-p-methylacetophenone with phenylhydrazine and its substituted derivatives

✍ Scribed by A. P. J. Hoogeveen


Book ID
104585196
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
491 KB
Volume
50
Category
Article
ISSN
0165-0513

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## Abstract Phenacyl bromide 1 reacts with ethyl cyanoacetate 2 in presence of piperidine catalyst to afford the hexa‐2,4‐diene derivative 5. Ethyl phenacylcyanoacetate 3 was obtained by reaction of 1 with the sodium salt 6. Compound 3 reacts with hydrazines and trichloroacetonitrile to afford the