Some reactions of N2 · H2O+ ions
✍ Scribed by J.L. McCrumb; P. Warneck
- Publisher
- Elsevier Science
- Year
- 1981
- Weight
- 472 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0020-7381
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## Abstract The gas‐phase reactions of hydrated electrons with carbon dioxide and molecular oxygen were studied by Fourier transform ion cyclotron resonance (FT‐ICR) mass spectrometry. Both CO~2~ and O~2~ react efficiently with (H~2~O)~__n__~^−^ because they possess low‐lying empty π\* orbitals. Th
We report the observation of the O-+H,O+OH-+OH ion-molecule reaction following photodissociation of 0, within the 0: .H20 ion-dipole complex. Photoexcitation of the 0~ A % ,+X 'lIn dissociative transition in the 200-300 nm region initiates the reaction. The 0-'H20 reaction intermediate is the domina