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Some reactions of benzaldehyde acetals with alkyl-lithium reagents; a stereospecific olefin synthesis from 1,2-diols

โœ Scribed by Hines, James N.; Peagram, Michael J.; Thomas, Eric J.; Whitham, Gordon H.


Book ID
118121275
Publisher
Royal Society of Chemistry
Year
1973
Weight
798 KB
Category
Article
ISSN
1472-7781

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โœ Shigekazu Ito; Kozo Toyota; Masaaki Yoshifuji ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 177 KB ๐Ÿ‘ 1 views

The reactions of 2,3-dichloro-1,4-diphospha-1,3-butadiene, which is sterically protected with the 2,4,6-tri-t-butylphenyl group, with some nucleophiles, including alkyllithium reagents and lithium aluminum hydrides, afforded 1,2-diphosphinoacetylenes or 3-phosphino-1-phosphaallenes.