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ChemInform Abstract: Reactions of a Sterically Protected 2,3-Dichloro-1,4-diphospha-1,3-butadiene with Some Alkyl and Hydrido Lithium Reagents.

โœ Scribed by Shigekazu Ito; Kozo Toyota; Masaaki Yoshifuji

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
31
Category
Article
ISSN
0931-7597

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Reactions of a sterically protected 2,3-
Reactions of a sterically protected 2,3-dichloro-1,4-diphospha-1,3-butadiene with some alkyl and hydrido lithium reagents
โœ Shigekazu Ito; Kozo Toyota; Masaaki Yoshifuji ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 177 KB ๐Ÿ‘ 1 views

The reactions of 2,3-dichloro-1,4-diphospha-1,3-butadiene, which is sterically protected with the 2,4,6-tri-t-butylphenyl group, with some nucleophiles, including alkyllithium reagents and lithium aluminum hydrides, afforded 1,2-diphosphinoacetylenes or 3-phosphino-1-phosphaallenes.

ChemInform Abstract: Synthesis and React
ChemInform Abstract: Synthesis and Reactions of Some 4-Chloro-4-alkoxycarbonyl-1,2-diaza-1, 3-butadienes.
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1997 carboxylic acid esters carboxylic acid esters (acyclic compounds) P 0360 ## 46 -095 Synthesis and Reactions of Some 4-Chloro-4-alkoxycarbonyl-1,2diaza-1, 3-butadienes. -A simple two-step preparation of the new title compounds (III), which prove to be stable, versatile and reactive nucleophil