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Some problems with 1,2-dibromoethane residue analysis

โœ Scribed by Suzuki, Takashi; Ishizaka, Takashi; Sasaki, Kumiko; Saito, Yukio


Book ID
126101577
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
524 KB
Volume
37
Category
Article
ISSN
0021-8561

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The coupling reaction of polyisoprenyllithium with 1,2-dibromoethane (DBE) gives a multimodal molecular weight distribution (MWD). Species with molecular weights three and four times (P 3 , P 4 ) higher than the base polymer (P) are present beside the main expected one with double molecular weight (