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Some New Reactions of Methylsulfinyl and Methylsulfonyl Carbanion 1

✍ Scribed by Chaykovsky, Michael; Corey, E. J.


Book ID
127096526
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
320 KB
Volume
28
Category
Article
ISSN
0022-3263

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## Abstract The chloromethyl __trans__‐β‐styryl sulfone carbanion reacts with benzaldehyde and acrylonitrile under phase‐transfer catalysis conditions to give 2‐phenyl‐3‐(__trans__‐β‐styrylsulfonyl)oxirane and bis(2‐cyanoethyl)chloromethyl __trans__‐β‐styryl sulfone, respectively, and with nitroare