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Formation of 3,5,5-trimethyl derivatives of dihydrouracil nucleosides by reaction with methylsulfinyl carbanion and methyl iodide

✍ Scribed by Raymond P. Panzica; Leroy B. Townsend; D.L. Von Minden; M.S. Wilson; James A. McCloskey


Book ID
115745502
Publisher
Elsevier Science
Year
1973
Weight
335 KB
Volume
331
Category
Article
ISSN
0005-2787

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Reactions of 1,1,3,3-tetrakis(dimethylam
✍ Fred Rosche; Gernot Heckmann; Ekkehard Fluck; Bernhard NeumΓΌller πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 618 KB

1, I , 3,3-Tetrakis (dimethylamino)-I k5,3k5-diphosphete, 1, reacts with diphenylchlorophosphane to yield I , I , 33tetrakis (dimethylamino)-4-diphenylphos-phany1-I,2-dihydro-3k5-[1,3]diphosphetium chloride, 2, or, depending on the reaction conditions, the isomer compound 3. The cation of 2 is depro