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Some Mechanistic Aspects of the Reaction of Anhydrides with Nucleophiles 1

✍ Scribed by Denney, Donald B.; Greenbaum, Michael A.


Book ID
125981299
Publisher
American Chemical Society
Year
1957
Tongue
English
Weight
614 KB
Volume
79
Category
Article
ISSN
0002-7863

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The reaction of alkoxycarbonylmethylentriphenylphosphonium ylides 1 with alkyl propynoates 2 in dichlormethane proceeds via [2+2]cycloaddition rather than Michael addition, to lead to stabilised phosphonium ylides. In the course of our investigations into the reactivity of acetylendicarboxilic acid