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Mechanistic aspects of the reaction of acids with some platinum-acetylene complexes

✍ Scribed by Tripathy, P. B.; Roundhill, D. M.


Book ID
126944254
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
249 KB
Volume
92
Category
Article
ISSN
0002-7863

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The reaction of alkoxycarbonylmethylentriphenylphosphonium ylides 1 with alkyl propynoates 2 in dichlormethane proceeds via [2+2]cycloaddition rather than Michael addition, to lead to stabilised phosphonium ylides. In the course of our investigations into the reactivity of acetylendicarboxilic acid