A T-shaped planar complex of ethyne and Cl\* has been isolated in a mixture of the substances using a pulsed-nozzle, FT microwave spectrometer and character&d through its rotational spectrum. Rotational constants (A,, Bc, Cc), centrifugal distortion constants ( AJ, A,K, a,), and Cl-nuclear quadrupol
Some generalisations of the Jacobson radical for seminearrings and semirings
β Scribed by Willy G. van Hoorn
- Publisher
- Springer-Verlag
- Year
- 1970
- Tongue
- French
- Weight
- 704 KB
- Volume
- 118
- Category
- Article
- ISSN
- 0025-5874
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Rate constants have been measured in aqueous solutions for the reactions of the carbonate radical, COs'-, with several saturated alcohols and one cyclic ether as a function of temperature. Arrhenius pre-exponential factors ranged from 2 X lo8 to 1 X lo9 e mol-' s-l and activation energies ranged fr
The pyrolysis of n-propyl nitrate and tert-butyl nitrite at very low pressures (VLPP technique) is reported. For the reaction n-PrON02 A nPrO + NO2 the high-pressure rate expression at 300"K, log k, (sec-l) = 16.5 -40.0 kcal/mole/2.3 RT, is derived. The reaction tert-BuONO -% tert-BuO + N O was stud