## Abstract Titanium slurries, prepared by reduction of titanium chlorides with LiAlH~4~, are not only effective in couplings of ketones and aldehydes to alkenes, but also in reductive couplings and reductions of other functional groups.
โฆ LIBER โฆ
Some deoxygenation reactions with low-valent titanium (titanium trichloride/lithium tetrahydroaluminate)
โ Scribed by McMurry, John E.; Silvestri, Michael G.; Fleming, Michael P.; Hoz, Tova; Grayston, Michael W.
- Book ID
- 126335896
- Publisher
- American Chemical Society
- Year
- 1978
- Tongue
- English
- Weight
- 931 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0022-3263
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Mediated by low-valent titanium. generated from TiC13ILiA14. ammonia is incorporated into benzophenone to give N-(diphenylmethy1ene)-N-ldiphenylmethyl) amine in a synthetically useful reaction. A good yield 165 % ) requires that the temperatures of the reaction stages are well controled and that amm