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Some Chloromethyl Ethers of Nitro Alcohols and the Preparation of Mixed Acetals from Them

โœ Scribed by Hodge, E. B.


Book ID
115313385
Publisher
American Chemical Society
Year
1948
Tongue
English
Weight
359 KB
Volume
70
Category
Article
ISSN
0002-7863

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Use of 2-phenylsulphonyl cyclic ethers i
โœ Dearg S. Brown; Steven V. Ley; Sadie Vile; Mervyn Thompson ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 856 KB

2-Phenylsulphonyl cyclic ethers undergo facile displacement of the sulphonyl group by alcohols, in the presence of magnesium bromide etherate and sodium bicarbonate in tetrahydrofuran, to give good yields of the corresponding acetals. The preparation of tetrahydro-pyran and -furan ethers typically