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New Catalytic Methods for the Preparation of Acetals from Alcohols and Aldehydes

โœ Scribed by Li, Yonghong; Zhang, Xiaojun; Ren, Tianrui; Zhou, Jiaju


Book ID
111913728
Publisher
Taylor and Francis Group
Year
2006
Tongue
English
Weight
93 KB
Volume
36
Category
Article
ISSN
0039-7911

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A new method for the synthesis of ฮฑ-thio
โœ Tsuyoshi Satoh; Ko-ichi Kubota ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 148 KB

A two-step and high-yield method for the synthesis of ฮฑ-thio aldehydes from aldehydes with one-carbon elongation is realized by using chloromethyl phenyl sulfoxide as a one-carbon homologating agent. The ฮฑ-thio aldehydes are easily converted to desulfurized alcohols with Bu 3 SnH and AIBN in refluxi