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Some aspects of discreteness-of-charge and ion-size effects for ions adsorbed at charged metal/aqueous electrolyte interfaces

✍ Scribed by Samuel Levine; W. Ronald Fawcett


Book ID
108343205
Publisher
Elsevier Science
Year
1979
Weight
943 KB
Volume
99
Category
Article
ISSN
0022-0728

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Solvent free energies for electron trans
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Solvent free energies for electron transfer reactions at the water/Pt interface are calculated using molecular dynamics umbrella sampling for different ion charges and external electric fields. In all cases, the free energy curves as a function of solvent coordinate are in reasonable agreement with