The discreteness-of-charge effect at charged aqueous interfaces II. Single adsorbed ion species on mercury
โ Scribed by S. Levine; K. Robinson
- Publisher
- Elsevier Science
- Year
- 1973
- Weight
- 873 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0022-0728
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๐ SIMILAR VOLUMES
The inner or compact region at the charged mercury/aqueous electrolyte interface is usually regarded as havinga dielectric constant which is considerably smaller than the value for bulk water and which increases with distance from the mercury boundary. In the previous papers of this series 1"2, henc
The rate constant k should not be confused with the variable of integration k in this paper, as in (2.3) or (5.4). Similarly the transfer coefficient c~ differs from the a in (2.4).
Experimental data on surface tension available from the literature and generated in the present study are analyzed to estimate the applicability of adsorption models, based on the Frumkin equation, to nonionic and ionic surfactants and their mixtures. Optimization programs based on the least-squares