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Some applications of multidimensional gas chromatography to the enrichment of minor components in essential oil analysis

โœ Scribed by Bicchi, C. ;D'Amato, A. ;Frattini, C. ;Nano, G. M. ;Pisciotta, A.


Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
347 KB
Volume
12
Category
Article
ISSN
0935-6304

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โœฆ Synopsis


The use of multidimensional gas chromatography (MDGC) forthe analysis of essential oils is gaining in importance. A rarely used application consists in the enrichment of minor components through a MDGC system provided with a cold trap between trap column and analytical column. Under suitable conditions, in fact, the cold-trap can store a trapped compound (or a fraction) for a long time. Consequently, the same fraction can be heart-cut from several successive chromatographic runs on the first column and stored together in order to accumulate trace compounds; afterwards the accumulated fraction can be injected in the analytical column. The possibilities of this technique will be illustrated through some examples of analysis of complex essential oils.


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Comparing the composition of essential oils obtained by headspace gas chromatography (HSGC) and conventional hydrodistillation from needles of Pinus sylvestris L., a selective loss of low boiling terpene hydrocarbons can be observed by the latter technique. HSGC is therefore more suitable for quanti