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Solvolysis of α-Bromo-p-aminostyrene. Mesomeric vinyl cations, Part IV

✍ Scribed by C. A. Grob; H. R. Pfaendler

Publisher
John Wiley and Sons
Year
1971
Tongue
German
Weight
567 KB
Volume
54
Category
Article
ISSN
0018-019X

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📜 SIMILAR VOLUMES

Mesomeric Vinyl Cations. Part II. Solvol
Mesomeric Vinyl Cations. Part II. Solvolysis of 2-bromo-1, 3-butadienes
✍ C. A. Grob; R. Spaar 📂 Article 📅 1970 🏛 John Wiley and Sons 🌐 German ⚖ 713 KB

## Abstract In contrast to 2‐bromo‐1, 3‐butadiene (**5**), the di‐, tri‐ and tetramethyl derivatives **6**–**11** show remarkable solvolytic reactivity. First order rate constants and products of these bromodienes in 80% ethanol have been determined. Rates are very sensitive to the ionising power o

Solvolysis and Isomerization of cis- and
Solvolysis and Isomerization of cis- and trans-1-Bromo-1-(p-anisyl)-propene (α-Bromoanethole) Mesomeric Vinyl Cations, Part V
✍ C. A. Grob; R. Nussbaumer 📂 Article 📅 1971 🏛 John Wiley and Sons 🌐 German ⚖ 507 KB

## Abstract The influence of a β‐methyl group on the reactivity of two stereoisomeric vinyl bromides has been studied. In 80% ethanol __cis__‐(**8**) and __trans__‐α‐bromoanethole (**9**) undergo first order reactions leading to __p__‐methoxypropiophenone (**15**), 1‐ethoxy‐1‐(__p__‐anisyl)‐propene