Mesomeric Vinyl Cations. Part II. Solvol
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C. A. Grob; R. Spaar
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Article
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1970
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John Wiley and Sons
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German
⚖ 713 KB
## Abstract In contrast to 2‐bromo‐1, 3‐butadiene (**5**), the di‐, tri‐ and tetramethyl derivatives **6**–**11** show remarkable solvolytic reactivity. First order rate constants and products of these bromodienes in 80% ethanol have been determined. Rates are very sensitive to the ionising power o