Solvolysis of trans-cyclooct-2-enyl 3,5-dinitrobenzoates
โ Scribed by Kenneth B. Wiberg; Takayuki Nakahira
- Book ID
- 104234905
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- French
- Weight
- 143 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Of the many solvolysis rate studies involving ally1 compounds, only two have examined the effect of extending conjugation. Vernon' has estimated that replacement of a p-methyl group by a phenyl group (1. and 2) increases the rate by a factor of gg. 140. Friedrich and WinsteIn have studied some spiro
H. C. Brown and G. Ham, J.Am. Chem,Soc, && 2735 (1956) found a cyclopentyl/ cyclohexyl rate ratio of 14. Cyclobutyl tosylate is 11 timae as reactive as cyclohexyl tosylate.' Correcting for the 7OO:l ratio found with I and III, one obtains a rate acceleration of 8X10' for cyclobutyl tosylate.