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Solvolysis of 2-(ω-alkoxyalkyl)-3-methyl-2-cyclohexenyl p-nitrobenzoates : Search for neighboring oxygen participation

✍ Scribed by Mladen Ladika; Branko Juršić; Dionis E. Sunko


Book ID
108372332
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
830 KB
Volume
43
Category
Article
ISSN
0040-4020

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✍ Mladen Ladika; Branko Juršić; Zlatko Mihalić; Dionis E. Sunko 📂 Article 📅 1986 🏛 Elsevier Science 🌐 French ⚖ 268 KB

As shown by kinetic and product analysis, the solvolysis of7 and 8 in m includes several competitive reactions, one of them being neighbofing sulfur participation and formation of intermediate cyclic sulfonium cation. Recently we have demonstrated' the absence of r-or n-participation in solvolysis o