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Solvolyses of 2-endo- and 2-exo-chloro-7-thiabicyclo[2.2.1]heptanes

✍ Scribed by Tabushi, Iwao; Tamaru, Yoshinao; Yoshida, Zenichi; Sugimoto, Takuji


Book ID
127388472
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
720 KB
Volume
97
Category
Article
ISSN
0002-7863

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Preparation of 1,2exo- and 1,2endo-Diiod
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## Abstract 1,2 __exo__‐Diiodo‐norbornane (**4**) was prepared from norcamphor hydrazone by oxidative iodination and subsequent rearrangement of the 2,2‐diiodo‐bicyclo [2.2.1]heptane (**2**). The stable α‐iodohydrazone **11** was obtained from 1‐iodo‐bicyclo[2.2.1]heptan‐2‐one (**10**), which itsel