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Solving the Mathematics of a Kinetic and Regiochemical Problem: The Dehydration Reaction of a cis-trans Mixture of 2-Methylcycloalkanols

โœ Scribed by Cawley, John J.


Book ID
121293010
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
69 KB
Volume
76
Category
Article
ISSN
0021-9584

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Reaction of trans-{PtH2[P(C6H11)3]2} wit
โœ A. Albinati; A. Musco; G. Carturan; G. Strukul ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 427 KB

## Carbon disulphide inserts into the Pt-H bond oj trans-{PtH,[P(C~,1)3]2} to give trans-{PtH(S,CH) [P(CJ113J2}. The X-ray structure shows that the -S2CH group is bonded to the metal through a sulfur atom as a monodentate thioformate anion. The kinetics of the carbon disulfide insertion have been in