Solvent Polarity Effects on Carbene/Ether– O -Ylide Equilibria
✍ Scribed by Hoijemberg, Pablo A.; Moss, Robert A.; Krogh-Jespersen, Karsten
- Book ID
- 126980861
- Publisher
- American Chemical Society
- Year
- 2012
- Tongue
- English
- Weight
- 322 KB
- Volume
- 116
- Category
- Article
- ISSN
- 1089-5639
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
An equilibrium is homogeneous when all components are either exclusively in the gas phase or exclusively in solution. For gas-phase equilibria, the ratio of the product concentrations for end and starting materials is constant at a given temperature (law of mass action of Guldberg and Waage, 1867).
Supramolecular Chemistry. Part 60. Solvent Effects on Crown Ether Complexations. -The complexation between potassium salts and 18-crown-6 in 14 different solvents is studied. The stability constant K increases by ¿ 104 from water to pure methanol or to propylene carbonate. Linear correlations are ob