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ChemInform Abstract: Supramolecular Chemistry. Part 60. Solvent Effects on Crown Ether Complexations.

✍ Scribed by V. P. SOLOV'EV; N. N. STRAKHOVA; O. A. RAEVSKY; V. RUEDIGER; H.-J. SCHNEIDER

Publisher: John Wiley and Sons
Year: 2010
Weight: 26 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199701035

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✦ Synopsis

Supramolecular Chemistry. Part 60. Solvent Effects on Crown Ether Complexations. -The complexation between potassium salts and 18-crown-6 in 14 different solvents is studied. The stability constant K increases by ¿ 104 from water to pure methanol or to propylene carbonate. Linear correlations are observed with standard Gibbs transfer energies of the metal ion from water to the given solvent. -(SOLOV'EV, V. P.; STRAKHOVA, N.

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