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Solvent isotope effect on the rate of methoxyl exchange between methyl borate and methanol

โœ Scribed by Hutton, William C.; Crowell, Thomas I.


Book ID
126267915
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
463 KB
Volume
100
Category
Article
ISSN
0002-7863

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The rate of oxygen exchange between truns-[Re(py),02]+ and solvent water in py-pyH' buffer solution follows simple first-order kinetics and both oxygens are equivalent. The half-life for isotopic oxygen exchange is about 12 h at a pH of 5.0, 25"C, and [pyl = 0.10 M. The observed rate constant for ex