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Solvent induced isomerization of 2-cyclohexen-1-ol to 3-cyclohexen-1-ol by a chiral lithium amide

โœ Scribed by Agha Zul-Qarnian Khan; Per I. Arvidsson; Per Ahlberg

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
233 KB
Volume
7
Category
Article
ISSN
0957-4166

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## Abstract Enzymatic hydrolysis of (ยฑ)โ€2,4,4โ€trimethylโ€2โ€cyclohexenyl acetate [(ยฑ)โ€3] with pig liver esterase yielded (__R__)โ€(+)โ€2,4,4โ€trimethylโ€2โ€cyclohexenโ€1โ€ol [(__R__)โ€2] and unchanged (__S__)โ€(โˆ’)โ€acetate (__S__)โ€3. Enantiomerically pure (__S__)โ€2 was converted into (__R__)โ€dihydroโ€ฮฑโ€ionone (