Raney Nickel Catalyzed hydrogen-deuterium exchange in a cerebroside and a monosaccharide is conducted under very mild conditions using a mixed solvent system and ultrasonic irradiation. The mild conditions appear to enhance the site selectivity of the exchange. Deuterium and tritium labelling of ca
Solvent-induced control of ultrasonic deuterium labelling
β Scribed by Eugene A. Cioffi
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 173 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
In this and subsequent papers the deuterium isotope effect is defined as h(D,H)=S(D)-h(H) following the convention used in referencing chemical shifts [ 101.
Deuterium and tritium labeling of carbohydrates and glycoconjugates has very wide applicability in the biochemical and biophysical fields. Carbohydrates function as receptors for a variety of hormones and play critical roles in cell recognition and differentiation. Deuterium labeled compounds are fr
## Abstract Chiral polyethyne derivatives with lyotropic liquidβcrystalline properties are found to be able to selfβassemble, forming two chiral organizations with opposite handedness in solid thin films by selection of the casting solvent and its concentration. After the film preparation, chiral o