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Solvent-induced deuterium isotope effects on 19F chemical shifts of some substituted fluorobenzenes. Formation of inclusion complexes

✍ Scribed by Poul E. Hansen; Heather D. Dettman; Brian D. Sykes

Publisher: Elsevier Science
Year: 1985
Weight: 648 KB
Volume: 62
Category: Article
ISSN: 0022-2364
DOI: 10.1016/0022-2364(85)90217-3

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## Abstract Sum‐over‐states perturbation and finite perturbation calculations, within the ‘Solvaton’ model, are presented for the variation of some ^17^O and ^19^F chemical shifts as a function of the dielectric constant of the medium. In general, the nuclear screening and charge are predicted to i